Nanostructured Cerium Oxide Based Catalysts: Synthesis, Physical Properties, and Catalytic Performance
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منابع مشابه
Synthesis and Catalytic Activity of Nanostructured Cerium Oxide
Cerium oxide (ceria, CeO 2-x where x is 0 to 0.5) has been one of the most widely used heterogeneous catalysts particularly in three way catalytic converters. Most of the catalytic traits can be attributed to two properties of ceria: first, the high mobility and storage capacity of oxygen within the lattice; second, the ease with which cerium changes between Ce 3+ and Ce 4+ states. These proper...
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Cerium oxide, or ceria (CeO x : x = 1.5 to 2), has been widely used as a heterogeneous catalyst. Ceria has several properties make it high catalytic active: the fluctuating valence of cerium, the high oxygen storage capacity and high oxygen mobility in the nonstoichiometric ceria. With the high abundance of cerium on earth crust, ceria is a highly effective alternative of the noble metal cataly...
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Traditional nanostructured design of cerium oxide catalysts typically focuses on their shape, size, and elemental composition. We report a different approach to enhance the catalytic activity of cerium oxide nanostructures through engineering high density of oxygen vacancy defects in these catalysts without dopants. The defect engineering was accomplished by a low pressure thermal activation pr...
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Silicoaluminophosphate (SAPO-34) molecular sieve doped with transition metals, Mn and Ni, with different molar ratios (Mn/Ni=0.33, 3) were investigated for their activity, selectivity and lifetime in biomethanol to olefins reaction. MnNiAPSO-34 nanostructured catalyst was synthesized by hydrothermal method and addition of metals was carried out by isomorphous substitution into the crystalline f...
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Several Fe-Ce catalysts for FT synthesis were prepared following two different methods: coprecipitation from Fe and Ce nitrate solutions and a physical mixture of pure Fe and Ce oxide precursors. Previously to CO hydrogenation, catalysts were activated in syngas (50 ml/min, H2/CO = 2) at 553 K for 1 h at atmospheric pressure. The iron phases developed after activation pretreatment were identifi...
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تاریخ انتشار 2016